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Accelerated aging of bio-oil from lignin conversion in subcr

Accelerated aging of bio-oil from lignin conversion in subcritical water, TAPPI JOURNAL March 2017

Journal articles
Magazine articles
Open Access
Preparing prehydrolyzed kraft dissolving pulp via phosphotungstic acid prehydrolysis from grape branches, TAPPI Journal January 2022

ABSTRACT: Dissolving pulp was successful prepared via phosphotungstic acid (PTA) prehydrolysis kraft (PHK) cooking followed by an elementary chlorine-free (ECF) bleaching process from grape branches. The effects of prehydrolysis temperature, reaction time, and PTA concentration that potentially affect the quality of dissolving pulp product on chemical components of pulp were studied via an orthogonal experiment. The structure of lignin was activated during the PTA prehydrolysis phase, and lignin was easily removed during the following cooking process. Thus, relatively mild conditions (140°C, 100 min) can be used in the cooking process. During the prehydrolysis phase, temperature exhibited the most significant influence on the cellulose purity of the obtained pulp fiber, followed by reaction time and PTA concentration. The optimized prehydrolysis conditions were as follows: prehydrolysis temperature, 145°C; reaction time, 75 min; and PTA concentration, 1 wt%. Whether the excessively high prehydrolysis temperature or prolonging the reaction time did not favor the retention of long chain cellulose, the delignification selectivity for the cooking process could not be further improved by excessive PTA loading. Under these prehydrolysis conditions, 94.1% and 29.0% for a-cellulose content and total yield could be achieved after the given cooking and bleaching conditions, respectively. Moreover, the chemical structure and crystal form of cellulose were scarcely changed after PTA prehydrolysis, which could be confirmed by results from Fourier transform infrared (FTIR) spectroscopy and X-ray diffraction (XRD). PTA prehydrolysis could be considered as an alternative method for preparing PHK dissolving pulp under relatively mild cooking conditions.

Journal articles
Magazine articles
Open Access
Development of paper quality parameter measurement in China, TAPPI Journal May 2022

ABSTRACT: Paper quality parameters are important indicators of paper production, such as paper moisture, basis weight, ash content, strength, and so on. This study focuses on the online measurement methods and development of paper basis weight, moisture, and ash measuring. First, the measurable paper parameters and quality control system products in China are analyzed. Then, the basis weight measurement methods, accuracy, and development are given in the range of 10~1000 g/m2. Third, the distinction between infrared and microwave methods for moisture measurement is discussed. Finally, the ash measurement is introduced. Production and consumption of tissue paper in China have continually increased during the past decade. Near-infrared light technology is mature for the measurement of paper parameters in the range of 10~200 g/m2 basis weight. However, the near-infrared online measurement of tissue paper is not widely used, and few tissue paper lines are equipped with this type of quality control system in China. Therefore, technology for near-infrared measurement of basis weight has a great potential market in the field of tissue paper production. This article analyzes the future development trend of near-infrared light in tissue paper basis weight measurement and summarizes the difficulties in near-infrared light measurement of tissue paper basis weight.

Journal articles
Magazine articles
Open Access
Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018

Using multistage models to evaluate how pulp washing after the first extraction stage impacts elemental chlorine-free bleach demand, TAPPI Journal November 2018

Journal articles
Magazine articles
Open Access
SCC susceptibility of chromized type 409 stainless steel in alkaline chloride solutions at ambient temperature and pressure, TAPPI Journal August 2023

ABSTRACT: Biomass hydrothermal liquefaction (HTL) is operated in a harsh reaction medium that contains hot pressurized water, inorganic acidic or basic catalyst, and inorganic/organic corrosive components released during the conversion. Candidate alloys for this application require suitable resistance to both corrosion and stress corrosion cracking (SCC) to withstand the HTL process conditions (250°C•374°C and 4•22 MPa). Ferritic iron-chromium (Fe-Cr) steels are more prone to corrosion but less susceptible to SCC compared to austenitic iron-chromium-nickel (Fe-Cr-Ni) steels. Chromizing can significantly reduce corrosion of Type 409 stainless steel (Fe-11Cr) in a simulated aqueous HTL solution. The objective of this study is to determine the SCC susceptibility of chromized Type 409 stainless steel, relative to the bare (non-chromized) case. The slow strain rate testing (SSRT) technique was used for this purpose. For simplicity of experimentation, SSRT was conducted using simulated HTL water containing 800 ppm potassium chloride (KCl), 1 M potassium carbonate (K2CO3), and 10 wt% acetic acid at ambient temperature and pressure. Complementary potentiodynamic polarization measurements and surface analysis by X-ray photoelectron spectros-copy (XPS) were also made to help interpret the SSRT results. The SSRT results show no significant difference in SCC susceptibility, regardless of the starting surface. Thus, chromizing, while significantly reducing the corrosion of Type 409 stainless steel, does not adversely affect SCC susceptibility, at least under the conditions tested.

SHORT-TIME COATING DEWATERING: A NOVEL TEST METHOD AND MODEL, 2008 Advanced Coating Fundamentals Symposium

SHORT-TIME COATING DEWATERING: A NOVEL TEST METHOD AND MODEL, 2008 Advanced Coating Fundamentals Symposium

Latex Dispersions as Carriers for Glucose Oxidase Oxygen Scavenging Systems, 2008 Advanced Coating Fundamentals Symposium

Latex Dispersions as Carriers for Glucose Oxidase Oxygen Scavenging Systems, 2008 Advanced Coating Fundamentals Symposium

Characterization of Ink Adhesion Failure; Effect of Pre-dampening of Carbonate Containing Coatings , 2008 Advanced Coating Fundamentals Symposium

Characterization of Ink Adhesion Failure; Effect of Pre-dampening of Carbonate Containing Coatings , 2008 Advanced Coating Fundamentals Symposium

Effect of Particle Size Distribution and Packing Compression on Fluid Permeability: A Comparison of Experiments and Monte-Carlo/Lattice-Boltzmann Simulations, 2008 Advanced Coating Fundamentals Symposium

Effect of Particle Size Distribution and Packing Compression on Fluid Permeability: A Comparison of Experiments and Monte-Carlo/Lattice-Boltzmann Simulations, 2008 Advanced Coating Fundamentals Symposium