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In-situ green synthesis and adsorption on methylene blue of copper-based metal organic framework/cellulose/chitosan (CCTSA/HKUST-1) composite aerogel, TAPPI Journal October 2024

ABSTRACT: In order to explore the application of metal-organic frameworks (MOFs) in environmental and water treatment fields, a new composite aerogel of HKUST-1/cellulose/chitosan (CCTSA/HKUST-1) with better hydrostability was synthesized by an in-situ synthesis method combining covalent cross-linking and solvothermal methods as an efficient adsorbent for methylene blue (MB). The composite aerogel (CCTSA) obtained by covalent cross-linking of cellulose (CE) and chitosan (CTS) exhibited excellent stability under strong acid and solvent-thermal conditions. With the increase of CTS content, it was beneficial to the in-situ synthesis of HKUST-1, as well as to increase the mass loading rate of HKUST-1 to 37.06%, while the Brunauer-Emmett-Teller (BET) specific surface area of CCTSA/HKUST-1 composite aerogel reached 945.123 m2·g-1, which was much higher than that of the CCTSA composite aerogel (14.489 m2·g-1). The CCTSA/ HKUST-1 composite aerogel exhibited excellent adsorption capacity (537.6 mg·g-1) on MB solution, and cyclic adsorption could be achieved. This study proposes a concept of valorization of alkaline peroxide mechanical pulping (APMP) waste liquor to hemicellulose-based hydrogel. This hemicellulose-based hydrogel exhibits a sensitive temperature/pH dual response. Hemicellulose-based hydrogels swell or shrink through the change of hydrogen bond/electrostatic repulsion/charge screening. They also show good water absorption and water retention properties.

TAPPI Journal Summaries, Paper360º September/October 2019

TAPPI Journal Summaries, Paper360º September/October 2019

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TAPPI Journal Summaries, Paper360º January/February 2017

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TAPPI Journal Summaries, Paper360º May/June 2018

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TAPPI Journal Summaries, November/December 2023 Paper360º

TAPPI Journal Summaries, November/December 2023 Paper360º

TAPPI Journal Summaries, Paper360º January/February 2024

Degradation of 2,4-dichlorophenol by melamine amine cellulos

Degradation of 2,4-dichlorophenol by melamine amine cellulose- immobilized lacasses, TAPPI JOURNAL October 2017

We’ve Got Good Chemistry: Innovations Papermakers Need to Know About, Paper360º March/April 2020

We’ve Got Good Chemistry: Innovations Papermakers Need to Know About, Paper360º March/April 2020